Characterization of Thin-Film Copper/Cuprous Oxide Photovoltaic Cell by Thermal Oxidation

Autores/as

  • Amechi, Bright U. Autor/a
  • Alabraba, M. A. Autor/a

Resumen

Copper-Cuprous Oxide (Cu2O/Cu) thin film photovoltaic cells were fabricated using thermal oxidation method for the Cu2O deposition. The copper sheet approximately ~1mm thick, were oxidized in air at a temperature between 900oC – 1050oC.  Oxide films formed between temperatures 1000°C and 1050°C were observed to consist entirely of Cu2O and showed p-type semiconductor while those grown below 900°C consists of a mixture of cupric oxide (CuO, though not strictly considered in this paper. In addition, the junctions on Cu2O were prepared by graphite carbon paste method obtained from used dry cells. The graphs of current – voltage and capacitance – voltage characteristics of schottky barrier diode obtained from the fabrication are presented. The results obtained indicate that cells of possible practical interest will have an oxide of a micron grown at relatively high temperatures. It was also deduced that the copper/cuprous oxide fabricated by the thermal oxidation method is a metal – semiconductor (or Schottky) diode with all the characteristics.

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Referencias

Boltaks, A. I. (1961). Diffusion in semiconductors. Intosearch Ltd.

Fernando, C. A. N., & Wetthasinghe, S. K. (2000). Investigation of photochemical characteristics of n-type Cu₂O films. Solar Energy Materials & Solar Cells, 63, 299–308.

Fortin, E., & Masson, D. (1982). Photovoltaic effects in Cu/Cu₂O solar cells grown by anodic oxidation. Solid State Electronics, 25(4), 281–283.

Ikata, E. S. (1987). Characterization of cuprous oxide by anodic oxidation (Unpublished master's thesis). University of Port Harcourt, Choba.

Jayatissa, A. H., Guo, K., & Jayasuriya, A. C. (2009). Fabrication of cuprous and cupric oxide thin films by heat treatment. Applied Surface Science, 255(23), 9474–9479.

Liang, B. J., Kishi, N., Soga, T., & Jimbo, T. (2012). Thin cuprous oxide films prepared by thermal oxidation of copper foil with water. Nagoya Institute of Technology Repository.

Musa, A. O., Akomolafe, T., & Carter, M. J. (1998). Production of cuprous oxide, a solar cell material by thermal oxidation and a study of its physical and electrical properties. Solar Energy Materials and Solar Cells, 51(3–4), 305–316.

Pacheo, M. J. G., Morales-Sánchez, J. E., Gernandez, J., & Ruiz, F. (2010). Synthesis of copper nanoparticles using soybeans as a chelant agent. Materials Letters, 64(12), 1361–1364.

Rakhshani, A. E. (1986). Preparation, characteristics and photovoltaic properties of cuprous oxide – A review. Solid-State Electronics, 29, 7.

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Publicado

2025-07-05

Cómo citar

Characterization of Thin-Film Copper/Cuprous Oxide Photovoltaic Cell by Thermal Oxidation. (2025). Nigerian Journal of Oil and Gas Technology, 2(2), 139-146. https://rsustnjogat.org/ojs/index.php/home/article/view/69